172-29, 41 FR 15996, Apr. B116 The use of non specification, sift-proof dump or hopper type vehicles, and sift-proof roll-on/roll-off bulk bins, which must be covered by a tarpaulin, metal cover, or equivalent means is authorized for the transportation of spent bleaching earth by motor vehicle. IBCs must be packed in closed freight containers or a closed transport vehicle. (2) To the extent a special provision imposes limitations or additional requirements on the packaging provisions set forth in column 8 of the 172.101 table, packagings must conform to the requirements of the special provision. Ch 6.0b Flashcards | Quizlet This provision may be used for both domestic and international shipments. B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars, equipped with a venting arrangement (including flame arrestors) approved by the Associate Administrator are also authorized. PDF Hazard Classifications Used in Hazmat Table, Column 3 This content is from the eCFR and is authoritative but unofficial. (i) These provisions apply to the transportation of hazardous materials in IM and UN Specification portable tanks. Overview of Hazardous Material Transportation Regulations For the purpose of this special provision, vehicles are self-propelled apparatus designed to carry one or more persons or goods. Learn more about the eCFR, its status, and the editorial process. TP19 The calculated wall thickness must be increased by 3 mm at the time of construction. 56 A means to interrupt and prevent detonation of the detonator from initiating the detonating cord must be installed between each electric detonator and the detonating cord ends of the jet perforating guns before the charged jet perforating guns are offered for transportation. The tank car specification may be marked to indicate a test pressure of 20.68 Bar (300 psig). 362 This entry applies to liquids, pastes or powders, pressurized with a propellant that meets the definition of a gas in 173.115. 157 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.151(b)(1)(i) of this subchapter for inner packagings may be increased to 5 kg (11 pounds). Shipments made in accordance with this Special provision are excepted from the requirements of 173.60(b)(4) of this subchapter. 151 If this material meets the definition of a flammable liquid in 173.120 of this subchapter, a FLAMMABLE LIQUID label is also required and the basic description on the shipping paper must indicate the Class 3 subsidiary hazard. 136 This entry applies only to articles, machinery, and apparatus containing hazardous materials as an integral element of the article, machinery, or apparatus. As a The material must be packaged so that the percentage of diluent does not fall below that stated in the approval at any time during transportation. is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Insulating materials may not promote corrosion to steel when wet. air bag inflators, air bag modules, seat-belt pretensioners, and pyromechanical devices containing Class 1 (explosive) materials or materials of other hazard classes. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate; 0-5% sodium or potassium perchlorate; 0-17% hexamine nitrate or monomethylamine nitrate; 5-30% water; 2-15% fuel; 0.5-4% thickening agent; 0-10% soluble flame suppressants; and trace additives. Radiation detection systems containing such detectors are not subject to any other requirements of this subchapter provided they are packed in accordance with paragraph c of this special provision. A2 Single packagings are not permitted on aircraft. Size of marking on bulk package must conform to 172.302(b) of this subchapter. 197 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). Test of type 3(c) is not required. A51 For aircraft batteries, irrespective of the quantity limitations specified in Column (9A) of the 172.101 Table or 175.75(c), wet cell batteries, UN2794 or UN2795, up to a limit of 100 kg net mass per package may be transported aboard passenger aircraft. Title 49 was last amended 2/03/2023. The cargo transport unit shall display the UN number in a manner in accordance with 172.332 of this subchapter and be placarded on two opposing sides. N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. This entry does not apply to capacitors that by design maintain a terminal voltage (e.g., asymmetrical capacitors.). However, sediments remaining in the tank that meet the definition for a hazardous material are subject to the applicable regulations of this subchapter. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name. US DOT's Hazardous Materials Regulations (HMR) list more than 3,000 shipping names for regulated materialsfrom acetal to zirconium tetrachloride. Lead compounds that have a solubility of 5% or less in accordance with this special provision are not subject to the requirements of this subchapter that pertain to Marine Pollutants. Column 8 f. The properties of mechanical strength mentioned in this special provision shall be tested using a prototype of a receptacle and/or dispenser filled to nominal capacity, by increasing the temperature until the specified pressures are reached. 22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash point above 50 C (122 F). Table I - Maximum Ambient Temperature - Gasoline. The identification number used must be consistent on package markings, shipping papers and emergency response information. Column 7 of the 172.101 Hazmat Table lists the special provisions that apply to an individual proper shipping name. 106 The recognized name of the particular explosive may be specified in addition to the type. A copy of the approval must accompany each shipment. 79 This entry may not be used for mixtures that meet the definition for oxidizing gas. 49 CFR -172.101 Hazardous Materials Table info - MaselliWeb (iii) Constructing the battery with terminals that are recessed or otherwise protected so that the terminals will not be subjected to damage if the package is dropped. Note also that this exception does not apply to batteries that have been reconditioned for reuse. Cargo and portable tanks must have a design pressure of at least 1,207 kPa (175 psig). 2 Except when authorized under Special Provision 41. The organic peroxide must be type D, E, or F, not requiring temperature control. (ii) One bottle for every two hours of production, or for every 2,500 bottles produced, must be tested by dropping a bottle filled to 98 percent capacity with water from a height of 1.2 meters (3.9 feet) onto solid concrete directly on the closure. The in-page Table of Contents is available only when multiple sections are being viewed. TP36 For material assigned this portable tank special provision, portable tanks used to transport such material may be equipped with fusible elements in the vapor space of the portable tank. The caps must not contain more than an average of twenty-five hundredths of a grain of explosive composition per cap; c. The caps must be packed inside packagings constructed of cardboard not less than 0.013-inch in thickness, metal not less than 0.008-inch in thickness, non-combustible plastic not less than 0.015-inch in thickness, or a composite blister package consisting of cardboard not less than 0.013-inch in thickness and non-combustible plastic not less than 0.005-inch in thickness that completely encloses the caps; d. The minimum dimensions of each side and each end of the cardboard packaging must be 1/8th inch in height or more; e. The number of caps inside each packaging must be limited so that not more than 10 grains of explosives composition may be packed into one cubic inch of space, and not more than 17.5 grains of the explosive composition of toy caps may be packed in any inner packaging; f. Inner packagings must be packed in outer packagings meeting PG II performance criteria; g. Toy caps may be packed with non-explosive or non-flammable articles provided the outer packagings are marked as prescribed in this paragraph; h. Toy paper caps of any kind must not be packed in the same packaging with fireworks; i. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). TP18 The temperature of this material must be maintained between 18 C (64.4 F) and 40 C (104 F) while in transportation. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). developer resources. Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meeting the following criteria: (1) A flammable liquid is a liquid having a flashpoint of not more than 93 C (200 F); (2) A flammable solid is a solid that meets the criteria in 173.124 of this subchapter; or. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized provided that the lading is covered with a nitrogen blanket. If the air bag inflator unit satisfactorily passes the series 6(c) test, it is not necessary to repeat the test on the air bag module. 328 When lithium metal or lithium ion batteries are contained in the fuel cell system, the item must be described under this entry and the appropriate entries for Lithium metal batteries contained in equipment or Lithium ion batteries contained in equipment. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. The Code of Federal Regulations (CFR) is the official legal print publication containing the codification of the general and permanent rules published in the Federal Register by the departments and agencies of the Federal Government. Such articles must comply with the following requirements: (1) The water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C (59 F); (2) The minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C (59 F); (3) Each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. Codes in Column 7 may be numbers, or a combination of letters and numbers. b. The letter Z shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in 178.702(a)(2) of this subchapter to specify the material used for the other packaging. The coal tar pitch compound must be in a solid mass during transportation. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. (b) Description of codes for special provisions. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in. TP32 Portable tanks may be used subject to the following conditions: a. B57 Class 115A tank car tanks used to transport chloroprene must be equipped with a non-reclosing pressure relief device of a diameter not less than 305 mm (12 inches) with a maximum rupture disc pressure of 310 kPa (45 psig). W41 When offered for transportation by water, this material must be packaged in bales and be securely and tightly bound with rope, wire or similar means. B8 Packagings shall be made of nickel, stainless steel, or steel with nickel, stainless steel, lead or other suitable corrosion resistant metallic lining. B53 Packagings must be made of either aluminum or steel. No label is needed where the table shows the word NONE. Transport vehicles must be vented to prevent accumulation of vapors at a poisonous or flammable concentration. package). (4) IB Codes and IP Codes. a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. Portable tanks containing solidified methacrylic acid must not be reheated during transportation. TP12 This material is considered highly corrosive to steel. Outage must be at least 5 percent at 98 C (208 F). A stimulating mechanism must be used to initiate one article in the middle of the packaging. When a plus sign is assigned to mix- (8) A code containing the letters TP refers to a portable tank special provision for UN or IM Specification portable tanks that is in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. B13 A nonspecification cargo tank motor vehicle authorized in 173.247 of this subchapter must be at least equivalent in design and in construction to a DOT 406 cargo tank or MC 306 cargo tank (if constructed before August 31, 1995), except as follows: a. Packagings equivalent to MC 306 cargo tanks are excepted from the certification, venting, and emergency flow requirements of the MC 306 specification. Lading in unlined tanks must be inhibited so that the corrosive effect on steel is not greater than that of hydrofluoric acid of 65 percent concentration. TP2 a. In addition, the column 5 reference is modified to read III on those occasions when this material is offered for transportation or transported by highway or rail. 6 This material is poisonous-by-inhalation and must be described as an inhalation hazard under the provisions of this subchapter. A212 UN 2031, Nitric acid, other than red fuming, with more than 20% and less than 65% nitric acid intended for use in sterilization devices only, may be transported on passenger aircraft irrespective of the indication of forbidden in columns (9A) of the 172.101 table provided that: a. You can learn more about the process N89 When steel UN pressure receptacles are used, only those bearing the H mark are authorized. (contains magnesium, magnesium nitrides) in PG II or III may be packaged in sift-proof bulk packagings that prevent liquid from reaching the hazardous material with sufficient venting to preclude dangerous accumulation of flammable, corrosive or toxic gaseous emissions such as methane, hydrogen and ammonia. 421 This entry will no longer be effective on January 2, 2023, unless we terminate it earlier or extend it beyond that date by notice of a final rule in the Federal Register. The batteries inside the cargo transport unit are not subject to marking or labelling requirements of part 172 subparts D and E of this subchapter. It must not freeze at temperatures above 15 C (5 F). N43 Metal drums are permitted as single packagings only if constructed of nickel or monel. (3) B codes. Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). 422 When labelling is required, the label to be used must be the label shown in 172.447. Specification 110A500W tanks must be stainless steel. The standards for transporting a single bulk hazardous material for blasting by cargo tank motor vehicles (CTMV); and. result, it may not include the most recent changes applied to the CFR. For non-pressurized lighters containing a Class 3 (flammable liquid) material, its design, description, and packaging must be approved by the Associate Administrator prior to being offered for transportation or transported in commerce. Component cells of the battery must be of a type proved to meet the respective testing requirements of the Manual of Tests and Criteria, part III, subsection 38.3 (IBR, see 171.7 of this subchapter). 49 CFR 173.240 - Bulk packaging for certain low hazard solid materials. This entry does not apply to life saving appliances described in 173.219 (UN2990 and UN3072). Radiation detectors transported as individual components must be transported as follows: (1) They must be packed in a sealed intermediate plastic liner with sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents. A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. While columns 8 and 7 of the Hazardous Materials Table are used to determine authorized packaging for most HazMat (more on that in a little bit), some methods of transportation, HazMat quantities, and specific operations rely on other methods. (d) Used or spent battery exception. These provisions can be classified even further with each form of transportation. For a battery whose voltage (electrical potential) exceeds 9 volts -, (1) When contained in a device, the device must be packaged in a manner that prevents unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit breakers, etc. Specifically, you seek clarification on the implementation of special provision IP15which is listed in Column 7 of the 172.101 Hazardous Materials Table (HMT)as it applies when this material is packaged in a composite intermediate bulk container (IBC) with a rigid inner receptacle. e. When transported by highway, rail, vessel, or as cargo on an aircraft, neutron radiation detectors containing not more than 1 gram of boron trifluoride, including those with solder glass joints are not subject to any other requirements of this subchapter provided they meet the requirements in paragraph a of this special provision and are packed in accordance with paragraph b of this special provision. 440 When this material is transported by tank car, the offeror must ensure each tank car is remotely monitored for pressure and location. 176 This entry must be used for formaldehyde solutions containing methanol as a stabilizer. 4 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone D (see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. switch to drafting.ecfr.gov. 368 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN3507 or UN2978. B45 Each tank must have a reclosing combination pressure relief device equipped with stainless steel or platinum rupture discs approved by the AAR Tank Car Committee. 50 Cases, cartridge, empty with primer which are made of metallic or plastic casings and meeting the classification criteria of Division 1.4 are not regulated for domestic transportation. Displaying title 49, up to date as of 3/02/2023. For Federal Register citations affecting 172.102, see the List of CFR Sections Affected, which appears in the Finding Aids section of the printed volume and at www.govinfo.gov. Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. Sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. A3 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed rigid and leakproof receptacles before packing in outer packagings. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. (3) A flammable gas is a gas that meets the criteria in 173.115 of this subchapter. 132 This description may only be used for ammonium nitrate-based compound fertilizers. Tables 1, 2, and 3 follow: 1 Flexible plastic (51H) Large Packagings are only authorized for use with flexible inner packagings. B27 Tanks must have a service pressure of 1,034 kPa (150 psig). TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following: Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively. An installed inflation cylinder that requires recharging must be filled in accordance with 173.301(l). Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the 172.101 Table. If a fuel cell engine is installed in a vehicle, the vehicle must be described using Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. A copy of the approval shall accompany the shipping papers. TP24 The portable tank may be fitted with a device to prevent the build up of excess pressure due to the slow decomposition of the hazardous material being transported. 16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Division 4.1 in accordance with 173.56 of this subchapter. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. c. A composite packaging 6PG2 (glass, porcelain or stoneware receptacles within a fiberboard box). citations and headings Subpart BTable of Hazardous Materials and Special Provisions 172.101 Purpose and use of haz-ardous materials table. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. TP9 A hazardous material assigned to special provision TP9 in Column (7) of the 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator. 381 For railroad flagging kits, see 173.184 (c) of this subchapter. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). quantity (RQ)", contains the reportable quantity (RQ), in pounds and kilograms, for each hazardous substance listed in Column 1 of TABLE 1. In addition to meeting the conditions in this provision, transport on cargo aircraft only may be authorized with prior approval of the Associate Administrator. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar; b. This includes vehicles transported in a packaging. 5101-5128, 44701; 49 CFR 1.81, 1.96 and 1.97. Insulating materials must not promote corrosion to steel when wet. 120 The phlegmatized substance must be significantly less sensitive than dry PETN. Column 7: Special provisions. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. 238 Neutron radiation detectors: Neutron radiation detectors containing non-pressurized boron trifluoride gas in excess of 1 gram (0.035 ounces) and radiation detection systems containing such neutron radiation detectors as components may be transported by highway, rail, vessel, or cargo aircraft in accordance with the following: a. Interior heating coils are not authorized. When there is an entry in this column, refer to Section 172.102 of the federal regulations for specific information. 5. (4) A code containing the letters IB or IP refers to a special provision that applies only to transportation in IBCs. The requirements of 172.203(m) and 172.505 of this subchapter do not apply. During transport, it must be protected from direct sunshine and stored (or kept) in a cool and well-ventilated place, away from all sources of heat. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). Specification IBCs and FIBCs are to be secured to a pallet. B2 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.